Beilstein J. Org. Chem.2015,11, 1833–1864, doi:10.3762/bjoc.11.199
have covered literature that appeared during the last seven years (2008–2014).
Keywords: Diels–Alderchemistry; green chemistry; natural products; olefin metathesis; polycycles; ring-rearrangement metathesis; Introduction
Transition metal–carbene complexes (Figure 1) introduced during the last two
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Graphical Abstract
Figure 1:
Ruthenium alkylidene catalysts used in RRM processes.
Beilstein J. Org. Chem.2014,10, 2235–2242, doi:10.3762/bjoc.10.232
application of cyclopropene tags to N-acylgalactosamine and N-acylglucosamine derivatives enabling the visualization of mucin-type O-glycoproteins and O-GlcNAcylated proteins through Diels–Alderchemistry. Whereas the previously reported cyclopropene-labeled N-acylmannosamine derivative leads to significantly
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Graphical Abstract
Scheme 1:
Principle of MOE with Ac4GlcNCyoc (1) and subsequent ligation by a DAinv reaction: The chemically m...